玩具法规当前进展_75.pdf

?CTI?BPA?A?AZO-Dyes?AZO Dyes?-?,?88/378/EEC?88/378/EEC?No?No 1907/2006(REACH)?CMR?CMR?CMR?CMR?CMR?0.1?CMR?CMR?1?2?5?76/768/EEC?8?/?19?8?/?19?/?b?/k?Pb?/?90mg/kg?Cd40mg/kg2009?7?1?phthalates?DBP,BBP,DEHP,DNOP,0.1%?,NO,DINP,DIDP?2008?4?1?HB2647?6?600mg/kg6?600mg/kg?2008?7?1?Pb?2008?7?1?2008?5?13?62?(?-?)?12?300mg/kg2009?7?1?Pb?100mg/kg2011?7?1?Pb?90mg/kg?0.009mg/cm22009?7?1?g?2008?6?2?08-106?12?2008?10?1?600ppm2009?7?1?300ppm?2009?7?1?300ppm2010?7?1?100ppm?12?600ppm?12?2009?7?1?90ppm?14?2008?10?17?600ppm?:15?/?CPSC?CPSC?8?14?8?14?CPSIA(Consumer Product Safety Improvement Act)?Safety Improvement Act)?CPSC?CPSC?CPSC?1.?(?)?0.06%(600 ppm)?180?(2009?2?10?)?0 03%(300)?1?(2009?8?14?)0.03%(300 ppm)?1?(2009?8?14?)?0.01%(100 ppm)?3?(2011?8?14?)?CPSC?2.?/?(?16 CFR 1303.1)?0.06%?0.009%?1?(2009?8?14?)?CPSC?3.?(2009?8?14?)?CPSC?90?(2008?11?12?)?CPSC?(2009?8?14?)?CPSC?120?2008?12?12?-?180?2009?2?10?-?180?(2009?2?10?)?(?)ASTM F963-07?(?4.2?4?)?CPSC?180?(2009?2?10?)?180?(2009?2?10?)?1?-2-?DEHP?1.?-2-?DEHP?DBP?BBP?0.1%?2.?DINP?DIDP?DNOP?0.1%?CPSC?1?1.?2.?3.?4.?2008?9?9?2008?9?9?:?0.1%?;?;1?-2-?DEHP2?DBP3?BBP3?BBP?0.1%?:?4?DINP5?DIDP6?DNOP?(CITIP INTI)?.?2007?9?20?18?90ppm?600ppm?600ppm3?600ppm2008?3?11?600ppm?90ppm?2008?6?2?14?CtU S AEAtliCANADAJAPANCountryU.S.AEuropean AustraliansCANADAJAPANStandardsASTM F963-07EN71 PART 3:1994AS/NZS ISO 8124-3:2003CHPAR.S.c.H-3 1998Japan Toy Safety Standard Part3:2002 Test MaterialsSurface coatingOther than Modeling claySurfacing coatingSurfacing coating,Test MaterialsSurface coatingmodeiling clay Modeling claySurfacing coatingInk and like used materialElementsMg/kg?ppm?Mg/kg?ppm?Mg/kg?ppm?Percentage?%?Mg/kg?ppm?Arsenic(As)25s25s25s0.1s25sMercury(Hg)60s60s25sN.D.60sSelenium(Se)500s500s500s0.1s500sAntimony(Sb)60s60s60s0.1s60sLead(Pb)600t?90s90s90s0.06t90sCadmium(Cd)75s75s50s0 1s75sCadmium(Cd)75s75s50s0.1s75sBarium(Ba)1000s1000s250s0.1s1000sChromium(Cr)60s60s25s-60s?Standard/directive/Act Materials appliedPhthalates requirement2005/84/ECAlllti idDBP+BBP+DEHP0 1%2005/84/ECAll plasticised materials in toys and childcare articlesDBP+BBP+DEHP0.1%DINP+DNOP+DIDP0.1%ST2002PVCDEHP0.1%?DINP0.1%EN14372Thermoplastcis DBP+BBP+DEHP+DINP+DNOP+DIDP0 1%DINP+DNOP+DIDP0.1%ASTM F963-07Pacifiers,rattles,teethersDEHP3%California health and safetyAll plasticised materialsDBP+BBP+DEHP0.1%California health and safety code All plasticised materials in toys and childcare articlesDBP+BBP+DEHP 0.1%DINP+DNOP+DIDP 120?2?2?(?)?Hazardous Products(Toys)Regulations,C.R.C.,c.931?Pb?Sb?As?Ba?Cd?Cr?Hg?Se?/(mg/kg)6001000100010001000?101000?EN71-3?ASTM963-07?0.07mol/L?0.07mol/L?5?37?37?20?2?2?10?2?2?10?8?8?5?600mg/kg?600mg/kg?10mg/kggg?10mg/kg?0.1-0.3g?50?0.07mol/l HCl?500?250?1m?/?PH?1.0-1.5?1h?37?2oC?0.1g?20ml 5%?HCl?1h?37?2oC?20ml 5%?HCl20?2?10min?0.45?ICP?0.45?ICP?(?)?(?)?(?)?()?(?)?(?)?/?/?2005/84/ECAll plasticised materials in toys andDBP+BBP+DEHP0.1%?2005/84/ECmaterials in toys and childcare articlesDINP+DNOP+DIDP0.1%?ST2002PVCDEHP0.1%?DINP0.1%?EN14372:2004Thermoplastcis DBP+BBP+DEHP+DINP+DNOP+DIDP0.1%?ASTM F963-07Pacifiers,rattles,teethersDEHP3%?California health and safety code?AB 1108?All plasticised materials in toys and childcare articlesDBP+BBP+DEHP0.1%DINP+DNOP+DIDP0.1%?(?)?:?(?)?1.?2.?3.?4.?5.?(?)?GC FID?GC MS?(?)?GC-FID?GC-MS?1.20ml/min?280?150?(?2min)?20?/min?300?(?5min)?280?250?(?)?(?)?1?DBP?C16H22O4278149?205?2231492?BBP?C19H20O4312149?206?2381493?DEHP?C24H38O4390149?167?2791494?DNOP?C24H38O4390149?261?279279?DNOP?5?DINP?C26H42O4418149?207?2932936?DIDP?C28H46O4446149?281?307307EN 71-9,10,11?EN 71-9?EN 71-10?EN 71-11?EN 71-9,10,11?EN 71 9,10,11?150?0 52?0.5m2?EN 71-9,10,11?9,0,?3?EN 71-9,10,11?9,0,?EN 71-9,10,11?,?UV GCGC MS GC-MS LC LC-MS?raw material?semi-products?final products?final products?pigment)?(extender)()?(solvent)?(resin)?()?(master color)?Fl For example?wet paint?plastic?PVC?phthalates?PVC?phthalates?phthalates?(Testing)?(Testing)?(Process control)?(Traceability)?Test on materialProcess auditTest on final product?